5-Bromo-2-(4-fluorophenyl)-7-methyl-3-methylsulfinyl-1-benzofuran

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5-Bromo-2-methyl-3-(4-methylphenylsulfonyl)-1-benzofuran

In the title compound, C(16)H(13)BrO(2)S, the 4-methyl-phenyl ring makes a dihedral angle of 87.83 (6)° with the mean plane [mean deviation = 0.007 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds and Br⋯O contacts [3.099 (2) Å]. The crystal structure also exhibits π-π inter-actions between the furan and benzene rings of neighbouring mol-ecul...

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5-Bromo-3-(4-fluorophenylsulfonyl)-2-methyl-1-benzofuran

In the title compound, C(15)H(10)BrFO(3)S, the 4-fluoro-phenyl ring makes a dihedral angle of 76.51 (6)° with the plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak non-classical inter-molecular C-H⋯O hydrogen bonds and an aromatic π-π inter-action between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.540 (3) Å].

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5-Bromo-3-(4-chlorophenylsulfinyl)-2-methyl-1-benzofuran

In the title compound, C(15)H(10)BrClO(2)S, the 4-chloro-phenyl ring is oriented approximately perpendicular to the mean plane of the benzofuran ring [dihedral angle = 89.55 (9)°]. In the crystal, mol-ecules are linked through weak inter-molecular C-H⋯O hydrogen bonds and and a Br⋯Br contact [3.783 (3) Å].

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5-Bromo-3-(4-fluorophenylsulfinyl)-2-methyl-1-benzofuran

In the title compound, C(15)H(10)BrFO(2)S, the O atom and the 4-fluoro-phenyl group of the 4-fluoro-phenyl-sulfinyl substituent are located on opposite sides of the plane through the benzofuran fragment; the 4-fluoro-phenyl ring is approximately perpendicular to this plane [dihedral angle = 89.38 (6)°]. In the crystal, mol-ecules are linked by a Br⋯Br contact [3.4816 (5) Å], and weak inter-mole...

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